Will we have free time throughout the week?

Absolutely.  There is more ground to cover than usual as we are working our way from the capital of Chile all the way down to Torres Del Paine and Patagonia, but you will seek solace among the vineyards, cities, lakes, and penguins.  You will have plenty of time to do the things you want (i.e. explore, nap, read, relax, or enjoy happy hour).